THE HEMI-ADDUCT OF BIS(DIETHYLDITHIOCARBAMATO-S,S')-TELLURIUM(II) WITH 4,4'-BIPYRIDYL

Authors
RAJASHREE S KUMAR RK UDUPA MR SESHASAYEE R ARAVAMUDAN G
Citation
S. Rajashree et al., THE HEMI-ADDUCT OF BIS(DIETHYLDITHIOCARBAMATO-S,S')-TELLURIUM(II) WITH 4,4'-BIPYRIDYL, Acta crystallographica. Section C, Crystal structure communications, 52, 1996, pp. 707-709
Citations number
13
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
52
Year of publication
1996
Part
3
Pages
707 - 709
Database
ISI
SICI code
0108-2701(1996)52:<707:THOBW>2.0.ZU;2-U
Abstract
In the structure of dithiocarbamato-S,S')-tellurium(II)-4,4'-bipyridyl (2/1), [Te(C5H10NS2)(2)].-1/2C(10)H(8)N(2), the bipyridyl molecule wa s found to bridge two bis(diethyldithiocarbamato)tellurium moieties ce ntrosymmetrically, i.e. l-N:N')-bis(diethyldithiocarbamato-S,S')tellur ium. The N atom of the bipyridyl is very weakly coordinated to telluri um and this is the first instance of Te-N coordination observed in a t ellurium-dithiocarbamate complex. Each Te atom has an unusual planar-p entagonal arrangement of ligands around it.