The transmission and luminescence of spray-deposited thin (6 mum) CdS
films were studied below the gap (2.44 eV = 508 nm at 300 K) by the us
e of the 514.5 nm and 632.8 nm lines of an argon- and He-Ne laser, res
pectively. Oscillations with a frequency of about 0.03-0.05 Hz were ob
served in both effects at 300 K. The oscillations occur without any ex
ternal feedback and are driven exclusively by particlar properties of
the thin CdS films. An impurity band between 1.7 and 1.8 eV, which cau
ses a nonequilibrium state between the generation and recombination ra
te, is found to be the origin of the selfinduced oscillation effect.