STEREOISOMERIC FLAVOR COMPOUNDS .74. 2-PHENYLPROPANOL, 2-PHENYLPROPANAL AND 2-PHENYLPROPANAL DIMETHYL ACETAL - STRUCTURE ELUCIDATION AND STRUCTURE-FUNCTION RELATIONSHIP

Citation
D. Bartschat et A. Mosandl, STEREOISOMERIC FLAVOR COMPOUNDS .74. 2-PHENYLPROPANOL, 2-PHENYLPROPANAL AND 2-PHENYLPROPANAL DIMETHYL ACETAL - STRUCTURE ELUCIDATION AND STRUCTURE-FUNCTION RELATIONSHIP, Zeitschrift fur Lebensmittel-Untersuchung und -Forschung, 202(4), 1996, pp. 266-269
Citations number
15
Categorie Soggetti
Food Science & Tenology
ISSN journal
00443026
Volume
202
Issue
4
Year of publication
1996
Pages
266 - 269
Database
ISI
SICI code
0044-3026(1996)202:4<266:SFC.22>2.0.ZU;2-7
Abstract
The direct enantioseparation of 2-phenylpropanol, 2-phenylpropanal and 2-phenylpropanal dimethyl acetal was achieved, using enantioselective gas chromatography and tyl-6-O-tert.butyldimethylsilyl]-beta-cyclodex trin (DIAC-beta-CD) or yl-6-O-tert.butyldimethylsilyl]-gamma-cyclodext rin (DIAC-gamma-CD) as the chiral stationary phase. Their odour charac teristics and threshold values were investigated by enantioselective g as chromatography/olfactometry. Starting from commercially available ( R)-2-phenylpropionic acid, enantiopure (R)-configured reference compou nds were synthesized.