D. Bartschat et A. Mosandl, STEREOISOMERIC FLAVOR COMPOUNDS .74. 2-PHENYLPROPANOL, 2-PHENYLPROPANAL AND 2-PHENYLPROPANAL DIMETHYL ACETAL - STRUCTURE ELUCIDATION AND STRUCTURE-FUNCTION RELATIONSHIP, Zeitschrift fur Lebensmittel-Untersuchung und -Forschung, 202(4), 1996, pp. 266-269
The direct enantioseparation of 2-phenylpropanol, 2-phenylpropanal and
2-phenylpropanal dimethyl acetal was achieved, using enantioselective
gas chromatography and tyl-6-O-tert.butyldimethylsilyl]-beta-cyclodex
trin (DIAC-beta-CD) or yl-6-O-tert.butyldimethylsilyl]-gamma-cyclodext
rin (DIAC-gamma-CD) as the chiral stationary phase. Their odour charac
teristics and threshold values were investigated by enantioselective g
as chromatography/olfactometry. Starting from commercially available (
R)-2-phenylpropionic acid, enantiopure (R)-configured reference compou
nds were synthesized.