Ne. Trofimenko et al., CORRELATION BETWEEN CARRIER POROUS STRUCTURE AND GAS-SENSITIVE PROPERTIES OF THERMOCATALYTIC GAS SENSORS, Sensors and actuators. B, Chemical, 30(3), 1996, pp. 191-193
In order to determine the correlation between the gas-sensitive proper
ties of the thermocatalytic gas sensor (TGS) and the porous structure
of the carrier, two types of carriers have been investigated. Their so
rptional parameters at different calcination temperatures have been st
udied. The parameters of the porous structure and the gas-sensitive pr
operties of the TGS are characterized by measurements of benzene vapou
r adsorption and methane oxidation using methane/air mixtures, respect
ively. The obtained data indicate that the sensitivity of the TGS is r
elated in some way with the structural parameters of the carrier (pore
size and diameter distribution). Carriers must have a sorption capaci
ty no less than 0.30 cm(3) g(-1), surface area of 100-140 m(2) g(-1) a
nd possess biporous pore-volume size distribution.