The possible liberation of highly toxic and mutagenic phosphine from p
utrefying media raises the question of its significance as a problem o
f hygiene. Free phosphine was established by gas chromatography as a u
niversal trace component in gas emitted from the anaerobic biosphere.
Sources of phosphine include landfills, compost processing, sewage slu
dge, animal slurry and river sediments. We detected maximum concentrat
ions in the order of 20 ppb (v/v).