The influence of cement fineness, the type and quantity of the sulphat
e agent used, and the clinker composition on the properties of Portlan
d cements was investigated after fine grinding in a ball mill and afte
r a high-pressure comminution process resembling interparticulate comm
inution. In general terms, interparticulate fine grinding led to a det
erioration in the flow behaviour of the cement paste (flow table sprea
d), to a shortening of the setting time, and to an increased initial r
eactivity of the cement, recognizable by the intensity of the ''first'
' peak during calorific measurement. Corresponding investigations with
pure clinker minerals showed that the reactivity of the C3S was incre
ased and the ettringite-monosulphate conversion was significantly acce
lerated by the interparticulate comminution.