V. Strehmel et al., ATTACHING OF FLEXIBLE CHAINS TO NOVOLACS ON THE BASIS OF BISPHENOL-A, Journal of applied polymer science, 60(8), 1996, pp. 1221-1229
Networks containing both flexible segments and rigid structures were s
ynthesized on the basis of bisphenol A novolacs and diglycidylether of
butanediol using imidazole as an accelerator. A stoichiometric ratio
between epoxy groups and phenolic groups of the novolacs leads to netw
orks with methylene bridges as network junctions. In contrast to this,
the same reaction with bisphenol A leads to completely soluble produc
ts. The glass transition temperature of this soluble material is consi
derably lower than the glass transition temperature of the networks. I
ncreasing content of methylene bridges in the novolacs leads to an inc
rease of the glass transition temperature of the networks and to a dec
rease of the Delta c(p) value at the glass transition. Furthermore, ep
oxy excess leads to networks with rubberlike properties. In addition,
AM1 calculation were performed to optimize the geometric structure of
the bisphenol A novolac used in the reaction with the diglycidylether.
It was found that conformations with intramolecular hydrogen bondings
exist between phenolic hydroxyl groups, which considerably influence
the reactivity of the novolac with the epoxy group. (C) 1996 John Wile
y & Sons, Inc.