Rb3C60 single crystals (T-c = 30.5 K) are investigated in the supercon
ducting state by scanning tunneling microscopy (STM) at 2.8 K. Electro
n tunneling spectroscopy (ETS) reveals a spatial variation of the supe
rconducting energy gap Delta. This behaviour is attributed to varying
stoichiometry on a scale of 50 nm. An investigation of a C-60 facet sh
ows that I(V) characteristics acquired between fullerene molecules exh
ibit additional gap states in contrast to those measured above molecul
es.