MULTIDOMAIN HYDROGEN-BOND FORMING METAL-CHELATES - X-RAY CRYSTAL-STRUCTURES OF DICYCLOPALLADATED 6-(2-AMINO-4-PHENYLAMINO-1,3,5-TRIAZINYL)]PYRAZINE (H(2)L) [PD(2)BR(2)L] AND 2-AMINO-4-PHENYLAMINO-1,3,5-TRIAZINYLIUM)]PYRIDINE DICHLORIDE

Authors
CHAN CW MINGOS DMP WHITE AJP WILLIAMS DJ
Citation
Cw. Chan et al., MULTIDOMAIN HYDROGEN-BOND FORMING METAL-CHELATES - X-RAY CRYSTAL-STRUCTURES OF DICYCLOPALLADATED 6-(2-AMINO-4-PHENYLAMINO-1,3,5-TRIAZINYL)]PYRAZINE (H(2)L) [PD(2)BR(2)L] AND 2-AMINO-4-PHENYLAMINO-1,3,5-TRIAZINYLIUM)]PYRIDINE DICHLORIDE, Chemical communications, (1), 1996, pp. 81-83
Citations number
15
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
1
Year of publication
1996
Pages
81 - 83
Database
ISI
SICI code
1359-7345(1996):1<81:MHFM-X>2.0.ZU;2-6
Abstract
Two new multi-domain alpha-diimine ligands capable of tri-hydrogen-bon ding interactions are described; the non-planar dicyclopalladated comp lex [Pd(2)Br(2)L] 3a (X = Br) has imposed chirality and contains a sho rt non-bonded 1,6-N ... N' contact of 2.75 Angstrom; the cationic (2a) form of the pseudo-terpyridine molecule 2 has a virtually planar cent ral core and is shown to be a potential host material.