WEAK COORDINATION OF A TELLUROKETONE IN AN ETA(1)-MODE COMPLEX - SYNTHESIS AND CHARACTERIZATION OF ACARBONYL(1,1,3,3-TETRAMETHYLINDANTELLONE)TUNGSTEN

Authors
MINOURA M KAWASHIMA T TOKITOH N OKAZAKI R
Citation
M. Minoura et al., WEAK COORDINATION OF A TELLUROKETONE IN AN ETA(1)-MODE COMPLEX - SYNTHESIS AND CHARACTERIZATION OF ACARBONYL(1,1,3,3-TETRAMETHYLINDANTELLONE)TUNGSTEN, Chemical communications, (2), 1996, pp. 123-124
Citations number
31
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
2
Year of publication
1996
Pages
123 - 124
Database
ISI
SICI code
1359-7345(1996):2<123:WCOATI>2.0.ZU;2-6
Abstract
Treatment of a stable telluroketone with W(CO)(5)-thf affords the titl e compound, the X-ray crystal structure of which shows eta(1),sigma-co mplexation and the trans influence of the weakly coordinated telluroke tone; the regeneration of a 'free' telluroketone by ligand exchange of the complex under mild conditions is also reported.