SYNTHESIS AND CHARACTERIZATION OF THE FIRST DISCRETE POTASSIUM THIOLATES DISPLAYING 3 DIFFERENT COORDINATION SPHERES AT POTASSIUM IN ONE MOLECULE

Authors
RUHLANDTSENGE K ENGLICH U
Citation
K. Ruhlandtsenge et U. Englich, SYNTHESIS AND CHARACTERIZATION OF THE FIRST DISCRETE POTASSIUM THIOLATES DISPLAYING 3 DIFFERENT COORDINATION SPHERES AT POTASSIUM IN ONE MOLECULE, Chemical communications, (2), 1996, pp. 147-148
Citations number
18
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
2
Year of publication
1996
Pages
147 - 148
Database
ISI
SICI code
1359-7345(1996):2<147:SACOTF>2.0.ZU;2-M
Abstract
Potassium hydride reacts with HSC6H2Pr3i-2,4,6 (HSR) in THF or thf-tme n (tmen = N,N,N',N'-tetramethylethylenediamine) to afford the first di screte, hexameric potassium thiolates [{K(SR)}(2){K(thf)(SR)}(2){K(thf >(2)(SR)}(2)] 3 and [{K(SR)}(2){K(thf)(SR)}(2){K(tmen)(SR)}(2)], 4 thf , exhibiting an unusual box-shaped structure with three different coor dination spheres for the three independent potassium atoms.