STERICALLY CROWDED MONOMERIC NEUTRAL BIS(BENZAMIDINATO) COMPOUNDS OF ALUMINUM, [PHC(NSIME(3))(2)](2)ALX (X=CL, H) - X-RAY CRYSTAL-STRUCTUREOF [PHC(NSIME(3))(2)]2ALH

Authors
DUCHATEAU R MEETSMA A TEUBEN JH
Citation
R. Duchateau et al., STERICALLY CROWDED MONOMERIC NEUTRAL BIS(BENZAMIDINATO) COMPOUNDS OF ALUMINUM, [PHC(NSIME(3))(2)](2)ALX (X=CL, H) - X-RAY CRYSTAL-STRUCTUREOF [PHC(NSIME(3))(2)]2ALH, Chemical communications, (2), 1996, pp. 223-224
Citations number
20
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
2
Year of publication
1996
Pages
223 - 224
Database
ISI
SICI code
1359-7345(1996):2<223:SCMNBC>2.0.ZU;2-8
Abstract
AlCl3 reacts with [PhC(NSiMe(3))(2)]Li(OEt(2)) to afford the is(N,N'-b is(trimethylsilyl)benzamidinato)aluminium chloro compound which, on tr eatment with KBEt(3)H, yields the structurally characterized monomeric hydride derivative, [PhC(NSiMe(3))(2)]2AlH, whose reactivity towards unsaturated hydrocarbons illustrates the low electrophilicity of the a luminium and high basic character of the hydride group.