Dt. On et al., ELECTRON-TRANSFER BANDS OF TITANIUM SITES IN DEHYDRATED SILICALITES AND IN TIO2-SIO2 GEL, Chemical communications, (3), 1996, pp. 299-300
The diffuse reflectance UV spectra of dehydrated titanium silicalites
of MFI structure are consistent with the presence of both open [Ti(OH)
(OSi)(3)] and closed [Ti(OSi)(4)] tetrahedral titanium sites, the clos
ed sites seem to be the only-ones occurring in TiO2-SiO2 silica gel.