LINEAR TRINUCLEAR 3-CENTERED METAL-METAL MULTIPLE BONDS - SYNTHESIS AND CRYSTAL-STRUCTURE OF [M(3)(DPA)(4)CL-2] [M=RU-II OR RH-II, DPA=BIS(2-PYRIDYL)AMIDO ANION]

Authors
SHEU JT LIN CC CHAO I WANG CC PENG SM
Citation
Jt. Sheu et al., LINEAR TRINUCLEAR 3-CENTERED METAL-METAL MULTIPLE BONDS - SYNTHESIS AND CRYSTAL-STRUCTURE OF [M(3)(DPA)(4)CL-2] [M=RU-II OR RH-II, DPA=BIS(2-PYRIDYL)AMIDO ANION], Chemical communications, (3), 1996, pp. 315-316
Citations number
21
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
3
Year of publication
1996
Pages
315 - 316
Database
ISI
SICI code
1359-7345(1996):3<315:LT3MMB>2.0.ZU;2-E
Abstract
The synthesis and X-ray crystal structures of the linear trinuclear me tal complexes, [M(3)(II)(dpa)(4)Cl-2] (M = Ru or Rh), with a syn-syn b is(2-pyridyl)amido (dpa) ligand, possessing a short M-M-M three-centre d multiple bond [Ru-Ru 2.2537(5) Angstrom; Rh-Rh 2.3990(5) Angstrom] a re described.