AUXILIARY-CONTROLLED DIASTEREOSELECTION BY N-(1-PHENYLETHYL) IN GRIGNARD ADDITIONS TO 2-O-BENZYLGLYCERALDEHYDE IMINES

Authors
VEITH U LEURS S JAGER V
Citation
U. Veith et al., AUXILIARY-CONTROLLED DIASTEREOSELECTION BY N-(1-PHENYLETHYL) IN GRIGNARD ADDITIONS TO 2-O-BENZYLGLYCERALDEHYDE IMINES, Chemical communications, (3), 1996, pp. 329-330
Citations number
35
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
3
Year of publication
1996
Pages
329 - 330
Database
ISI
SICI code
1359-7345(1996):3<329:ADBNIG>2.0.ZU;2-7
Abstract
Grignard reagents add to 2-O-benzylglyceraldehyde N-(1-phenylethyl)imi nes in high yield at normal or high pressure (12 kbar); threo vs. eryt hro selectivity is governed by the (R)- or (S)-1-phenylethyl substitue nt.