AN UNUSUAL THERMODYNAMIC PREFERENCE OF CHIRAL N-ARYLSULFONYL CIS-3-ALKYL-2-VINYLAZIRIDINES OVER THEIR TRANSISOMERS - PALLADIUM(0)-CATALYZEDEQUILIBRATION REACTIONS

Authors
MIMURA N IBUKA T AKAJI M MIWA Y TAGA T NAKAI K TAMAMURA H FUJII N YAMAMOTO Y
Citation
N. Mimura et al., AN UNUSUAL THERMODYNAMIC PREFERENCE OF CHIRAL N-ARYLSULFONYL CIS-3-ALKYL-2-VINYLAZIRIDINES OVER THEIR TRANSISOMERS - PALLADIUM(0)-CATALYZEDEQUILIBRATION REACTIONS, Chemical communications, (3), 1996, pp. 351-352
Citations number
13
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
3
Year of publication
1996
Pages
351 - 352
Database
ISI
SICI code
1359-7345(1996):3<351:AUTPOC>2.0.ZU;2-B
Abstract
Palladium (0)-catalysed reactions of N-alkylsulfonyl- or N-arylsulfony l-3-alkyl-2-vinylaziridines reveal that 2,3-cis-isomers are more stabl e than the corresponding 2,3-trans-isomers in accord with ab initio ca lculations.