[CU(H(2)DPPD)(ETA(1)-OCLO3)]CLO4 - THE FIRST CRYSTALLOGRAPHICALLY CHARACTERIZED PHOSPHINE COMPLEX OF COPPER(II) S[2-(DIPHENYLPHOSPHINO)PHENYL]PROPANE-1,3-DIAMINE)

Authors
PILLONI G BANDOLI G TISATO F CORAIN B
Citation
G. Pilloni et al., [CU(H(2)DPPD)(ETA(1)-OCLO3)]CLO4 - THE FIRST CRYSTALLOGRAPHICALLY CHARACTERIZED PHOSPHINE COMPLEX OF COPPER(II) S[2-(DIPHENYLPHOSPHINO)PHENYL]PROPANE-1,3-DIAMINE), Chemical communications, (3), 1996, pp. 433-434
Citations number
5
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
3
Year of publication
1996
Pages
433 - 434
Database
ISI
SICI code
1359-7345(1996):3<433:[-TFCC>2.0.ZU;2-B
Abstract
The title complex 2, easily obtained by controlled potential oxidation of the copper(I) precursor [Cu(H(2)dppd)]BF4 1, in perchlorate medium , crystallizes as a C6H6 monosolvate from dichloroethane-benzene, (2a) , or as a CH2Cl2 hemisolvate from dichloromethane-toluene (2b), to giv e dark-red crystals which have been structurally characterized by X-ra y crystallography.