NOVEL VINYLATION OF A MERCURY(II) CENTER IN [S2WS2HGCL2](2-) BY ACETONE - SYNTHESIS AND STRUCTURE OF [PPH(4)](2)[S2WS2HG(CH=CH2)(2)].0.5ME(2)CO AND ITS TOPOCHEMICAL CONVERSION INTO [PPH(4)](2)[S2WS2HG(C-CH)(2)].0.5MECHO

Authors
GHOSH I MISHRA R PODDAR D MUKHERJEE AK MUKHERJEE M BHATTACHARYYA R
Citation
I. Ghosh et al., NOVEL VINYLATION OF A MERCURY(II) CENTER IN [S2WS2HGCL2](2-) BY ACETONE - SYNTHESIS AND STRUCTURE OF [PPH(4)](2)[S2WS2HG(CH=CH2)(2)].0.5ME(2)CO AND ITS TOPOCHEMICAL CONVERSION INTO [PPH(4)](2)[S2WS2HG(C-CH)(2)].0.5MECHO, Chemical communications, (3), 1996, pp. 435-436
Citations number
29
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
3
Year of publication
1996
Pages
435 - 436
Database
ISI
SICI code
1359-7345(1996):3<435:NVOAMC>2.0.ZU;2-B
Abstract
Reaction of [PPh(4)](2)[S2WS2HgCl2] with acetone affords a yellow viny l complex [PPh(4)](2)[S2WS2Hg (CH=CH2)(2)]. 0.5Me(2)CO which on standi ng in a desiccator for 3-4 months transforms to a black ethynyl deriva tive [PPh(4)](2)[S2WS2Hg(C=CH)(2)]. 0.5MeCHO.