EQUATIONS FOR THE EQUILIBRIUM SURFACE PRESSURE INCREASE ON THE PENETRATION OF AN INSOLUBLE MONOLAYER BY A SOLUBLE SURFACTANT

This study addresses the penetration of a pre-existing insoluble monol ayer by a bulk soluble surfactant. It is shown that if the adsorption isotherm is known describing the partitioning of the soluble component between the interface and the bulk, the equation for the resulting in crease in surface pressure Delta pi can be derived using the Gibbs ads orption equation. The relationship is valid for any adsorption isother m. A framework for studying monolayer penetration is presented based o n these equations. Two example calculations are presented based on ads orption site models for the interface that allow closed form solutions for Delta pi(x(1),C-2), where C-2 is the molality of the soluble comp onent and x(1) is the fractional coverage of the insoluble component. First, a Langmuir model is posed, where the insoluble surfactant reduc es the adsorption of the soluble component. The Delta pi caused by the soluble surfactant at a given C-2 is exactly equal to the surface ten sion reduction caused by that surfactant in the absence of the insolub le monolayer. Second, a Frumkin model is posed, incorporating 1-2 inte ractions (between the insoluble (1) and soluble (2) components) and 2- 2 self-interactions. The model predicts enhanced Delta pi with x(1) fo r 1-2 cohesion and 2-2 repulsion and diminishing Delta pi with x(1) fo r 1-2 repulsion and 2-2 cohesion when compared with the surface tensio n reduction achieved by the soluble component alone. The Frumkin model is discussed as a means for quantifying synergistic adsorption into t he monolayer directly from a family of Delta pi curves for various, fi xed x(1) as a function of C-2. A brief discussion of data available in the literature is presented; the trends observed are in qualitative a greement with the theoretical framework.