Ethylene-vinyl alcohol (EVAL) membranes with particles-bonded structur
e are prepared by phase inversion from DMSO solvent into the coagulati
on baths of water and isopropanol (IPA) mixture. It is based on contro
lling the relative diffusion rate of solvent to nonsolvent and the liq
uid-liquid demixing area. Using this analysis, it can explain the effe
cts of adding IPA to the water bath on the formation of particles and
the suppression of macrovoids. The results proposed here are believed
to be valid also for other systems. Copyright (C) 1996 Elsevier Scienc
e Ltd.