Monocrystalline Er3+-doped CaF2 layers are grown on CaF2 substrates by
molecular beam epitaxy (MBE) with Er3+ concentration up to 31.2 wt%.
The lattice parameter and the crystallinity of the epilayers are inves
tigated by X-ray diffraction analysis, electron probe microanalysis, a
nd scanning electron microscopy. Green light emission at 538 nm is gen
erated by upconversion for the first time: using a 798 nm laser diode
pump. Maximum emission intensity at this wavelength is obtained at an
Er3+ concentration of 13.3 wt%.