P. Banacky et al., EFFECT OF NONADIABATICITY ON THE FERMI-EDGE PHOTOEMISSION AND TUNNELING SPECTRA OF SUPERCONDUCTORS, International journal of quantum chemistry, 58(5), 1996, pp. 487-496
Temperature dependence of the experimental photoemission spectra of th
e high-T-c superconductors have been interpreted and simulated by the
recently formulated molecular nonadiabatic theory of the electron-vibr
ational interaction. The change of the spectral feature below T-c' par
ticularly formation of the narrow, near Fermi surface (FS) edge, peak
separated by the dip from a broad spectral band at higher binding ener
gies has been shown to be the consequence of the nonadiabatic electron
-phonon coupling and corresponding properties of the nonadiabatic pola
rons. Simulation yields very good fit to the experimental temperature-
dependent spectra, with the calculated value of the gap 30.5 meV. (C)
1996 John Wiley & Sons, Inc.