Ad. Rodriguez et Jj. Soto, ISOLATION AND STRUCTURE OF ACEROPTERINE, A RARE PSEUDOPTERANE ALKALOID FROM THE CARIBBEAN SEA PLUME PSEUDOPTEROGORGIA-ACEROSA (PALLAS), Tetrahedron letters, 37(16), 1996, pp. 2687-2690
Acetopterine (1) is a new tetracyclic pseudopterane alkaloid isolated
from the purple sea plume Pseudopterogorgia acerosa collected in Puert
o Rico. Its structure has been determined by spectroscopic methods. Th
e unique transposed nature of the lactone function in 1 was establishe
d by two-dimensional 1 H-1-H-1 and H-1-C-13 NMR correlation experiment
s and confirmed by mass spectral analysis. Copyright (C) 1996 Elsevier
Science Ltd.