STEREOSPECIFIC CONSTRUCTION OF STEREOGENIC VICINAL QUATERNARY CARBON-ATOMS - ENANTIOSPECIFIC SYNTHESIS OF (-VALERANE())

Authors
SRIKRISHNA A VISWAJANANI R
Citation
A. Srikrishna et R. Viswajanani, STEREOSPECIFIC CONSTRUCTION OF STEREOGENIC VICINAL QUATERNARY CARBON-ATOMS - ENANTIOSPECIFIC SYNTHESIS OF (-VALERANE()), Tetrahedron letters, 37(16), 1996, pp. 2863-2864
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
16
Year of publication
1996
Pages
2863 - 2864
Database
ISI
SICI code
0040-4039(1996)37:16<2863:SCOSVQ>2.0.ZU;2-U
Abstract
Stereo- and enantiospecific synthesis of (+)-valerane starting from R- carvone utilising orthoester Claisen rearrangement and intramolecular diazo ketone cyclopropanation reactions for the construction of the tw o vicinal quaternary carbon atoms is described. Copyright (C) 1996 Els evier Science Ltd.