SCANNING AND ENERGY-DISPERSIVE EXAFS STUDIES OF ETHYL TRANSMETALATIONIN AN ALKENE OLIGOMERIZATION CATALYST

Authors
BOGG D CONYNGHAM M CORKER JM DENT AJ EVANS J FARROW RC KAMBHAMPATI VL MASTERS AF MCLEOD DN RAMSDALE CA SALVINI G
Citation
D. Bogg et al., SCANNING AND ENERGY-DISPERSIVE EXAFS STUDIES OF ETHYL TRANSMETALATIONIN AN ALKENE OLIGOMERIZATION CATALYST, Chemical communications, (5), 1996, pp. 647-648
Citations number
11
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
5
Year of publication
1996
Pages
647 - 648
Database
ISI
SICI code
1359-7345(1996):5<647:SAEESO>2.0.ZU;2-G
Abstract
Nickel K-edge XAS studies show that there is a rapid alkyl and beta-di ketonate exchange between [Ni(acac)(2)] and AlEt(2)(OEt) with [NiR(alk ene)(acac)] as the main species present under catalytic conditions.