AN AIR-STABLE, CATIONIC METALLACARBORANE WITHOUT A CHARGE-COMPENSATEDCARBORANE LIGAND

Authors
FERGUSON G POLLOCK J MCENEANEY PA OCONNELL DP SPALDING TR GALLAGHER JF MACIAS R KENNEDY JD
Citation
G. Ferguson et al., AN AIR-STABLE, CATIONIC METALLACARBORANE WITHOUT A CHARGE-COMPENSATEDCARBORANE LIGAND, Chemical communications, (5), 1996, pp. 679-681
Citations number
16
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
5
Year of publication
1996
Pages
679 - 681
Database
ISI
SICI code
1359-7345(1996):5<679:AACMWA>2.0.ZU;2-2
Abstract
The first air-stable, cationic rhodadicarborane complex, CN)-3,3-(PPh( 2)Me)(2)-3,1,2-closo-RhC2B9H11][SbF6] 1, which does not contain a 'cha rge-compensated' carborane ligand is synthesised and structurally char acterised by X-ray crystallography and spectroscopic techniques (IR an d NMR).