PIPERIDINE AMINOXYL RADICALS AS EPR PROBES FOR EXPLORING THE CAVITY OF A WATER-SOLUBLE CRYPTOPHANE

Authors
GAREL L VEZIN H DUTASTA JP COLLET A
Citation
L. Garel et al., PIPERIDINE AMINOXYL RADICALS AS EPR PROBES FOR EXPLORING THE CAVITY OF A WATER-SOLUBLE CRYPTOPHANE, Chemical communications, (6), 1996, pp. 719-720
Citations number
18
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
6
Year of publication
1996
Pages
719 - 720
Database
ISI
SICI code
1359-7345(1996):6<719:PARAEP>2.0.ZU;2-Y
Abstract
Piperidine aminoxyl radicals are reversibly bound in the cavity of a w ater-soluble cryptophane with an affinity of the order of 10(3) dm(3) mol(-1); the complexation equilibrium is slow on the EPR timescale and the magnitude of the nitrogen hyperfine splittings of the bound subst rates indicates that the cavity of this cryptophane has a polarity com parable to that of halogenated solvents.