SYNTHESIS AND CHARACTERIZATION OF A NEW DOUBLE-CUBANE MO-FE-S CLUSTERCOMPOUND, [NET(4)](3)[MO2FE6S8(MU-OME)(3)(SPH)(3)CL-3]

Authors
XU JQ ZHANG XG CAI H HU NH WEI CP YANG GY WANG TG
Citation
Jq. Xu et al., SYNTHESIS AND CHARACTERIZATION OF A NEW DOUBLE-CUBANE MO-FE-S CLUSTERCOMPOUND, [NET(4)](3)[MO2FE6S8(MU-OME)(3)(SPH)(3)CL-3], Chemical communications, (6), 1996, pp. 757-758
Citations number
19
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
6
Year of publication
1996
Pages
757 - 758
Database
ISI
SICI code
1359-7345(1996):6<757:SACOAN>2.0.ZU;2-4
Abstract
The new double-cubane cluster compound [NEt(4)](3)[Mo2Fe6S8(mu-OMe)(3) (SPh)(3)Cl-3] is synthesized from (NH4)(2)MoS4, FeCl3, Fe powder, S po wder, NaSPh and NEt(4)Br in MeOH-DMF, its crystal structure is determi ned by X-ray crystallography, and results of XPS indicate a valence st ate of +4 for Mo.