STUDY OF THE COMPLEXING PROPERTIES TOWARD RU-II OF NEW POLYDENTATE AMPHIPHILIC PHOSPHINES CONTAINING POLYETHER CHAINS - UNPRECEDENTED ETA(3) MODE OF BONDING OF THE NEW LIGAND PPH[(CH2)(3)CHME(2)][(CH2CH2O)(3)ME] AND STUDY OF ITS HEMILABILE CHARACTER

Authors
VALLS E SUADES J DONADIEU B MATHIEU R
Citation
E. Valls et al., STUDY OF THE COMPLEXING PROPERTIES TOWARD RU-II OF NEW POLYDENTATE AMPHIPHILIC PHOSPHINES CONTAINING POLYETHER CHAINS - UNPRECEDENTED ETA(3) MODE OF BONDING OF THE NEW LIGAND PPH[(CH2)(3)CHME(2)][(CH2CH2O)(3)ME] AND STUDY OF ITS HEMILABILE CHARACTER, Chemical communications, (6), 1996, pp. 771-772
Citations number
16
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
6
Year of publication
1996
Pages
771 - 772
Database
ISI
SICI code
1359-7345(1996):6<771:SOTCPT>2.0.ZU;2-M
Abstract
New polydentate amphiphilic phosphines containing polyether chains are prepared; unprecedented coordination and reactivity of the hemilabile ligand PPh[(CH2)(3)CHMe(2)][(CH2CH2O)(3)Me] are found; the eta(3) mod e of bonding of this ligand is demonstrated by X-ray crystallographic studies.