THE FIRST EFFICIENT PREPARATION OF VINYLAZIRIDINES VIA AN YLIDE ROUTE

Authors
LI AH DAI LX HOU XL
Citation
Ah. Li et al., THE FIRST EFFICIENT PREPARATION OF VINYLAZIRIDINES VIA AN YLIDE ROUTE, Chemical communications, (4), 1996, pp. 491-492
Citations number
34
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
4
Year of publication
1996
Pages
491 - 492
Database
ISI
SICI code
1359-7345(1996):4<491:TFEPOV>2.0.ZU;2-I
Abstract
A simple and direct method for preparation of vinylaziridines via an y lide route is described; dimethylsulfonium allylides or dimethylsulfon ium cinnamylides, produced in situ from the corresponding allylic sulf onium salts and solid potassium hydroxide in acetonitrile at room temp erature, react efficiently with N-sulfonylimines to furnish vinylaziri dines rapidly with excellent yields.