A NEW AND CONVENIENT BENZYLOXYALKYLATING AGENT INDUCED BY SAMARIUM DIIODIDE

Citation
T. Skrydstrup et al., A NEW AND CONVENIENT BENZYLOXYALKYLATING AGENT INDUCED BY SAMARIUM DIIODIDE, Chemical communications, (4), 1996, pp. 515-516
Citations number
28
Categorie Soggetti
Chemistry
Journal title
ISSN journal
13597345
Issue
4
Year of publication
1996
Pages
515 - 516
Database
ISI
SICI code
1359-7345(1996):4<515:ANACBA>2.0.ZU;2-3
Abstract
Benzyloxymethyl 2-pyridylsulfone reacts instantaneously and efficientl y with aliphatic ketones or aldehydes by simple titration with 2 equiv . of SmI2 to give the corresponding monoprotected vicinal diols in hig h yields.