ELECTROCHEMICAL SYNTHESIS OF TETRAKIS [N-METHYLBENZOTHIAZOLE-2(3H)-SELONE]SELENIUM(2- AN UNCOMMON DICATION CONTAINING THE MIXED-VALENCE SE-5 FRAMEWORK()TETRAFLUOROBORATE )

Authors
ADAMO C DEMARTIN F DEPLANO P DEVILLANOVA FA ISAIA F LELJ F LIPPOLIS V LUKES P MERCURI ML
Citation
C. Adamo et al., ELECTROCHEMICAL SYNTHESIS OF TETRAKIS [N-METHYLBENZOTHIAZOLE-2(3H)-SELONE]SELENIUM(2- AN UNCOMMON DICATION CONTAINING THE MIXED-VALENCE SE-5 FRAMEWORK()TETRAFLUOROBORATE ), Chemical communications, (7), 1996, pp. 873-874
Citations number
22
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
7
Year of publication
1996
Pages
873 - 874
Database
ISI
SICI code
1359-7345(1996):7<873:ESOT[>2.0.ZU;2-F
Abstract
The electrochemical oxidation of N-methylbenzothiazole-2(3H)-selone le ads to kis[N-methylbenzothiazole-2(3H-selone]selenium(2+) tetrafluorob orate showing an uncommon dication containing a non-cyclic square-plan ar Se-5 framework; both Mulliken and NBO population analyses explain t he relatively long Se-Se bond lengths between the central and the peri pheral selenium atoms.