SYNTHESIS AND CHARACTERIZATION OF A NOVEL RUTHENIUM ORGANOMETALLIC CIS-[RU(BPY)(2)(NPP)(CL)]CENTER-DOT-BF4 WHERE BPY=2,2'-BIPYRIDYL AND NPP=4-(N-PYRROLYL)PYRIDINE

Authors
ATKINS MJ HARWOOD DJ LOWRY RB
Citation
Mj. Atkins et al., SYNTHESIS AND CHARACTERIZATION OF A NOVEL RUTHENIUM ORGANOMETALLIC CIS-[RU(BPY)(2)(NPP)(CL)]CENTER-DOT-BF4 WHERE BPY=2,2'-BIPYRIDYL AND NPP=4-(N-PYRROLYL)PYRIDINE, Inorganica Chimica Acta, 244(2), 1996, pp. 277-280
Citations number
7
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganica Chimica Acta → ACNP
ISSN journal
00201693
Volume
244
Issue
2
Year of publication
1996
Pages
277 - 280
Database
ISI
SICI code
0020-1693(1996)244:2<277:SACOAN>2.0.ZU;2-4
Abstract
The ruthenium(II) complex cis-[Ru(bpy)(2)(npp) (Cl)](+) where bpy=2,2' -bipyridyl and npp=4-(N-pyrrolyl) pyridine has been isolated from the reaction between cis-dichlorbis(bipyridine)ruthenium and 4-(N-pyrrolyl ) pyridine and precipitated as the tetrafluoroborate salt. 270 MHz H-1 and C-13 NMR studies have been used to characterise this novel ruthen ium complex together with IR and Raman data. The 270 MHz H-1 NMR spect ra of 4-(N-pyrrolyl)pyridine and cis-[Ru(bpy)(2)(Cl)(2)] have also bee n recorded.