Tunneling images of the Si(111)-7 x 7 surface before and after laser i
rradiation have been compared. Examination of more than 300 unit cells
shows that the number of unit cells with missing center adatoms incre
ases by 2.48 eV laser pulse irradiation at fluences slightly above the
threshold laser fluence above which the emissions can be detected. No
indication of melting is observed in the unit cells with missing adat
oms. The results give clear evidence that laser-induced atomic emissio
ns from semiconductor surfaces are electronic and site selective.