A general approach has been developed to determine the conductivity of
individual nanostructures while simultaneously recording their struct
ure. Conventional lithography has been used to contact electrically si
ngle ends of nanomaterials, and a force microscope equipped with a con
ducting probe tip has been used to map simultaneously the structure an
d resistance of the portion of the material protruding from the macros
copic contact. Studies of individual carbon nanotubes demonstrate that
the structurally most perfect nanotubes have resistivities an order o
f magnitude lower than those found previously and that defects in the
nanotube structure cause substantial increases in the resistivity.