The thermal diffusivity, and specific heat, of polyethylene (76% cryst
allinity) containing dispersed particles (1%-15% volume fraction) of S
iO2 (diameter d=7,16,40 nm; 1,5,10 mu m), Fe (d=27 nm), Cu (n=53 nm),
and Ag (d=140 nm) have been measured using the laser flash method, and
the thermal relaxation method, in the temperature range of 4.2-300 K,
and the thermal conductivity was derived from the two quantities. The
thermal conductivity was decreased by the addition of particles, and
the decrease was more remarkable at lower temperatures for smaller par
ticles. The boundary thermal resistance between the particles and the
medium was derived from the change of conductivity due to the nm-diame
ter dispersed particles. The boundary resistance was independent of th
e size and the volume fraction of the particles, and was shown to be i
nversely proportional to the phonon specific heat of particle-disperse
d medium in over a wide range of temperatures. The phonon Debye temper
ature and the strength of the boundary thermal resistance were determi
ned by analyzing the data, and obtained results were quite reasonable.
(C) 1996 American Institute of Physics.