We have synthesized, by molecular beam epitaxy, Si/CaF2(111) multi-qua
ntum wells which are photoluminescent at room temperature after ageing
in air. In this article, we report on the structural properties and o
n a detailed optical study of these heterostructures. The photolumines
cence spectra for various confinements and the temperature dependence
of the lifetimes as a function of emission wavelength are described in
comparison with the corresponding characteristics of porous silicon a
nd hydrogenated amorphous silicon. A model based on quantum confinemen
t is proposed to explain the experimental data. (C) 1996 American Inst
itute of Physics.