EFFICIENT LANTHANIDE CATALYSIS IN AMINOACYL-TRANSFER FROM THE BIPYRIDINE-FUNCTIONALIZED AMIDE-SUBSTRATE TO ALCOHOLS AT AMBIENT-TEMPERATURE

Authors
ARAKI K KAJIKAWA T KAWAGUCHI S
Citation
K. Araki et al., EFFICIENT LANTHANIDE CATALYSIS IN AMINOACYL-TRANSFER FROM THE BIPYRIDINE-FUNCTIONALIZED AMIDE-SUBSTRATE TO ALCOHOLS AT AMBIENT-TEMPERATURE, Chemistry Letters, (4), 1996, pp. 295-296
Citations number
7
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
4
Year of publication
1996
Pages
295 - 296
Database
ISI
SICI code
0366-7022(1996):4<295:ELCIAF>2.0.ZU;2-8
Abstract
Lanthanide cations showed high catalytic activities in aminoacylation of alcohols by the amide-substrates having bipyridine as a metal chela tion site at 30 degrees C (first-order rate constants were 10(-4) s(-1 ) range at Ce3+/substrate = 0.2), yielding corresponding amino acid es ters almost quantitatively.