STUDIES ON LIGAND-LIGAND INTERACTIONS - FORMATION AND STABILITY OF SULFATE-PYRIDINE, OXALATE-PYRIDINE AND HEXACYANOFERRATE(II)-PYRIDINE COMPLEXES IN AQUEOUS-SOLUTION

Authors
FOTI C GIANGUZZA A GIUFFRE O
Citation
C. Foti et al., STUDIES ON LIGAND-LIGAND INTERACTIONS - FORMATION AND STABILITY OF SULFATE-PYRIDINE, OXALATE-PYRIDINE AND HEXACYANOFERRATE(II)-PYRIDINE COMPLEXES IN AQUEOUS-SOLUTION, Annali di chimica, 86(1-2), 1996, pp. 41-48
Citations number
20
Categorie Soggetti
Chemistry Analytical","Environmental Sciences
Journal title
Annali di chimica → ACNP
ISSN journal
00034592
Volume
86
Issue
1-2
Year of publication
1996
Pages
41 - 48
Database
ISI
SICI code
0003-4592(1996)86:1-2<41:SOLI-F>2.0.ZU;2-B
Abstract
A potentiometric study on ligand-ligand interactions in aqueous soluti on, is reported. The formation and stability of pyridine- sulphate, ox alate and hexacyanoferrate(ll) complexes has been investigated in the ionic strength range 0 less than or equal to 1 less than or equal to 0 .4 mol dm(-3) and at T = 25 degrees C. The results obtained showed tha t the complexing ability of protonated pyridine towards polyanions is similar to that of aliphatic amines and depends mainly on the charges involved in the formation reaction.