Yz. Wang et al., 3-DIMENSIONAL DYNAMIC CALCULATION OF THE EQUILIBRIUM SHAPE OF A COHERENT TETRAGONAL PRECIPITATE IN MG-PARTIALLY STABILIZED CUBIC ZRO2, Journal of the American Ceramic Society, 79(4), 1996, pp. 987-991
The equilibrium shape of a tetragonal precipitate coherently embedded
in a cubic matrix is examined in three dimensions by a computer simula
tion. Independent experimental data of Mg-partially stabilized ZrO2 ar
e used as the input parameters. The equilibrium shape is obtained by d
iffusional relaxation of an initially nonequilibrium spherical shape.
The relaxation is described through a generalized field kinetic model
which takes into account the transformation-induced elastic strain ari
sing from a cubic --> tetragonal crystal lattice rearrangement. Withou
t any a priori constraint on the geometry of the particle, the equilib
rium shape is shown to be a rotation disk formed by two cones with the
common base. It is far from the ellipsoidal shape assumed in the conv
entional analytical calculations based on Eshelby's model.