3-DIMENSIONAL DYNAMIC CALCULATION OF THE EQUILIBRIUM SHAPE OF A COHERENT TETRAGONAL PRECIPITATE IN MG-PARTIALLY STABILIZED CUBIC ZRO2

Citation
Yz. Wang et al., 3-DIMENSIONAL DYNAMIC CALCULATION OF THE EQUILIBRIUM SHAPE OF A COHERENT TETRAGONAL PRECIPITATE IN MG-PARTIALLY STABILIZED CUBIC ZRO2, Journal of the American Ceramic Society, 79(4), 1996, pp. 987-991
Citations number
26
Categorie Soggetti
Material Science, Ceramics
ISSN journal
00027820
Volume
79
Issue
4
Year of publication
1996
Pages
987 - 991
Database
ISI
SICI code
0002-7820(1996)79:4<987:3DCOTE>2.0.ZU;2-V
Abstract
The equilibrium shape of a tetragonal precipitate coherently embedded in a cubic matrix is examined in three dimensions by a computer simula tion. Independent experimental data of Mg-partially stabilized ZrO2 ar e used as the input parameters. The equilibrium shape is obtained by d iffusional relaxation of an initially nonequilibrium spherical shape. The relaxation is described through a generalized field kinetic model which takes into account the transformation-induced elastic strain ari sing from a cubic --> tetragonal crystal lattice rearrangement. Withou t any a priori constraint on the geometry of the particle, the equilib rium shape is shown to be a rotation disk formed by two cones with the common base. It is far from the ellipsoidal shape assumed in the conv entional analytical calculations based on Eshelby's model.