A ROUTE TO INVERSION FOR ROTATIONAL COLLISIONS USING HARD SHAPE POTENTIALS

Citation
Jc. Belchior et Jp. Braga, A ROUTE TO INVERSION FOR ROTATIONAL COLLISIONS USING HARD SHAPE POTENTIALS, Chemical physics, 205(3), 1996, pp. 401-406
Citations number
18
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
ISSN journal
03010104
Volume
205
Issue
3
Year of publication
1996
Pages
401 - 406
Database
ISI
SICI code
0301-0104(1996)205:3<401:ARTIFR>2.0.ZU;2-E
Abstract
The collision energy and the semiaxes of the hard ellipsoid are relate d by an analytical expression to obtain the parameters K, and either t he range of the potential, alpha, or the anisotropy of the potential, delta, for the potential model V(r, theta) = Ke(-alpha r)(1 + delta(2) cos(2) theta). The hard shape theory has been used to optimize the se miaxes of the ellipsoid by fitting cross sections to quantum results. This inversion procedure showed an average error of 7% in the alpha or delta parameter and about 15% in the K parameter.