HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHIC CHARACTERIZATION OF RHENIUM BIPYRIDINE COMPLEXES WITH PHOSPHORUS LIGANDS

Authors
HORI H KOIKE K ISHIZUKA M WESTWELL JR TAKEUCHI K IBUSUKI T ISHITANI O
Citation
H. Hori et al., HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHIC CHARACTERIZATION OF RHENIUM BIPYRIDINE COMPLEXES WITH PHOSPHORUS LIGANDS, Chromatographia, 43(9-10), 1996, pp. 491-495
Citations number
16
Categorie Soggetti
Chemistry Analytical","Biochemical Research Methods
Journal title
Chromatographia → ACNP
ISSN journal
00095893
Volume
43
Issue
9-10
Year of publication
1996
Pages
491 - 495
Database
ISI
SICI code
0009-5893(1996)43:9-10<491:HLCORB>2.0.ZU;2-#
Abstract
The high-performance liquid chromatography of fourteen rhenium complex es with phosphorus and 2,2'-bipyridine-derivative ligands has been exa mined. Good separation between these complexes was achieved by use of an ODS column with a 60:40 (v/v) mixture of MeOH and KH2PO4-NaOH buffe r as mobile phase. Linear correlations were observed between the capac ity factors of the mono-phosphorus complexes and Fujita's organicity/i norganicity ratios for the phosphorus ligands, revealing that Fujita's organicity/inorganicity parameters are useful for evaluating of the r etention behavior of these complexes.