R. Benrashid et al., FLAMMABILITY STUDY OF WALLBOARD CONTAINING THERMAL STORAGE MATERIALS - METHODS TO IMPROVE FLAME RETARDANCY OF TREATED WALLBOARD, Journal of fire sciences, 14(2), 1996, pp. 128-143
The introduction of thermal storage materials into wallboard can help
to control the temperature fluctuations in the heating and cooling of
a building. Thermal storage materials absorb or release heat in define
d temperature ranges. Wallboard was treated with thermal storage mater
ials, including hexadecane, 1-dodecanol, undecylenic acid, coconut oil
and silicone wax. These treatments involved absorption of the compoun
ds into the wallboard. The desired uptake of material into wallboard w
as approximately twenty-five percent. The uptake rate for silicone was
lower than for the other materials. Most of the energy storage materi
als are organic, therefore their odor, smoke production, and flammabil
ity are a concern. The flammability properties of wallboard samples co
ntaining these materials were studied using the E-662 NBS Smoke Chambe
r and the E162 Radiant Panel Test. The results showed that silicone wa
x, undecylenic acid and coconut oil treated wallboard samples have sup
erior flame retardent properties compared to wallboard treated with he
xadecane, and 1-dodecanol. Silicone wax has a lower latent heat for th
e phase change as measured by differential scanning calorimetry (DSC)
as compared with the other materials. To obtain better flammability pr
operties of treated wallboard, the surface was coated with an epoxy pa
int containing aluminum trihydrate or magnesium hydroxide. Radiant Pan
el studies showed a major reduction in flame spread factor (Fs) and he
at release factor (Q), compared to treated wallboard. However, NBS Smo
ke Chamber studies in the flaming and non-flaming mode did not show im
provement in smoke generation for coated samples. NBS Smoke Chamher re
sults showed that silicone treated wallboard without any coating yield
ed lower smoke in the non-flaming mode over other energy storage mater
ials, even when protected by a flame retardant paint. Dodecanol showed
lower smoke production in the flaming mode versus other samples.