SUPPRESSION OF SPIN-DIFFUSION IN SELECTED FREQUENCY BANDS OF NUCLEAR OVERHAUSER SPECTRA

Authors
VINCENT SJF ZWAHLEN C BODENHAUSEN G
Citation
Sjf. Vincent et al., SUPPRESSION OF SPIN-DIFFUSION IN SELECTED FREQUENCY BANDS OF NUCLEAR OVERHAUSER SPECTRA, Journal of biomolecular NMR, 7(2), 1996, pp. 169-172
Citations number
21
Categorie Soggetti
Biology,Spectroscopy
Journal title
Journal of biomolecular NMR → ACNP
ISSN journal
09252738
Volume
7
Issue
2
Year of publication
1996
Pages
169 - 172
Database
ISI
SICI code
0925-2738(1996)7:2<169:SOSISF>2.0.ZU;2-U
Abstract
A variant of two-dimensional nuclear Overhauser effect spectroscopy (N OESY) is described that yields information about cross-relaxation rate s between pairs of spins, while the migration of magnetization through several consecutive steps (spin diffusion via neighboring spins) is l argely suppressed. This can be achieved by inserting a doubly-selectiv e inversion pulse in a conventional NOESY sequence.