M. Ersoz et Hj. Duncan, TRANSPORT OF K+ ION AND SELECTIVE TRANSPORT OF ALKALI CATIONS THROUGHPERIDERM AND CUTICULAR MEMBRANES, Journal of controlled release, 39(1), 1996, pp. 9-15
The transport of KC ion against its concentration gradient through iso
lated periderm (PM) and cuticular (PFCM) membranes at different pH and
salt concentrations was investigated. The mean transport rate and tra
nsport fraction were calculated, and a tentative transport mechanism d
ue to fixed charges was proposed. The transport system depends on the
concentration gradient of K+ ions and H+ ions and the pH gradient was
the main driving force. This system is characterised by asymmetry of b
inding on both compartments of the membrane for the formation and diss
ociation of carrier carboxyl groups in the membrane matrix. These carr
ier groups are dissociated at high pH ranges. The studies were then ex
tended to examine the selective transport of alkali cations by using K
-Na and K-Li binary systems with various pH gradients. In the transpor
t of metal ions, the selectivity depends on both the hydrated ionic si
ze and the interaction between the carboxyl groups in the membrane and
the metal ions.