A method to determine the first order interaction parameters epsilon(C
)i according to the data of the influence of alloying elements upon th
e carbon solubility in liquid metals has been developed. The calculate
d results for iron based melts have been found to be in a good agreeme
nt with literature data. The epsilon(c)i values obtained for Mn-, Fe-,
Co- and Ni-based melts at 1873 K have been summarized in the series o
f linear equations depending on the number of alloying element in the
periodical system. Calculated metal activity in binary Me-C (Me = Mn,
Fe, Co, Ni) melts shows good agreement with literature data.