Jd. Bolton et Aj. Gant, HEAT-TREATMENT RESPONSE OF SINTERED M3 2 HIGH-SPEED STEEL COMPOSITES CONTAINING ADDITIONS OF MANGANESE SULFIDE, NIOBIUM CARBIDE, AND TITANIUM CARBIDE/, Powder Metallurgy, 39(1), 1996, pp. 27-35
Metal matrix composites based on a sintered M3/2 high speed steel (HSS
) and containing either single additions of TIG, NbC, or MnS particles
or combined additions of MnS + TIC or MnS + NbC were sintered to full
density and subjected to a conventional hardening heat treatment cycl
e of austenitisation, quenching, and double tempering. Relatively poor
hardnesses and strengths were obtained in any composites that contain
ed MnS particles, principally because of the weakening effects of MnS
particles in the structure but also as a result of decarburisation of
the steel matrix when oxygen introduced by the MnS particles reacted w
ith carbon. Composites that contained TIC were changed in structure so
that matrix M(6)C carbides were replaced by the less soluble MC carbi
de. They consequently showed slightly reduced hardening response compa
red to the baseline M3/2 HSS after heat treatment. Ball milling was ne
cessary ill powder mixtures that contained NbC to break up particle ag
glomerates. The resultant fine grain sized M3/2 + NbC materials produc
ed by sintering and heat treatment gave superior properties to both th
e normal M3/2 HSS and the other composites.