Synthesis by 'far from equilibrium' processes allows development of no
vel crystal structures and microstructures, leading to achievement of
enhanced physical and mechanical properties. Three far from equilibriu
m techniques are reviewed (with emphasis on the amount of departure fr
om equilibrium): mechanical alloying, plasma processing, and physical
vapour deposition. Consideration is given to solubility extension, for
mation of nanostructured grains, amorphisation, and synthesis of inter
metallic compounds. Examples are drawn from systems based on the light
metals aluminium, magnesium, and titanium.