ZIRCONOCYCLISATION - ACCESS TO NEW RACEMIC (DI) PHOSPHINES

Authors
MIRZAAGHAYAN M BOUKHERROUB R ETEMADMOGHADAM G MANUEL G KOENIG M
Citation
M. Mirzaaghayan et al., ZIRCONOCYCLISATION - ACCESS TO NEW RACEMIC (DI) PHOSPHINES, Tetrahedron letters, 37(18), 1996, pp. 3109-3112
Citations number
27
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
18
Year of publication
1996
Pages
3109 - 3112
Database
ISI
SICI code
0040-4039(1996)37:18<3109:Z-ATNR>2.0.ZU;2-E
Abstract
The bis-allylic 1 and the bis-propargylic 6 derivatives react with the zirconocene ''ZrCp(2)'' and lead, after electrophilic addition, to th e corresponding chiral trans heterocyclopentanes (M=Si,Ge,P) 3-5 and b is-methylenecyclopentanes 8. New chiral diphosphine 9 is obtained star ting from the intermediate complex 2 or the functionalized heterocyclo pentane 4. Copyright (C) 1996 Elsevier Science Ltd