OXIDATION OF ARYLAMIDOXIMES BY HYDROGEN-PEROXIDE AND HORSERADISH-PEROXIDASE IN WATER - EASY PREPARATION AND X-RAY STRUCTURE OF O-(ARYLIMIDOYL)ARYLAMIDOXIMES

Authors
BOUCHER JL VADON S TOMAS A VIOSSAT B MANSUY D
Citation
Jl. Boucher et al., OXIDATION OF ARYLAMIDOXIMES BY HYDROGEN-PEROXIDE AND HORSERADISH-PEROXIDASE IN WATER - EASY PREPARATION AND X-RAY STRUCTURE OF O-(ARYLIMIDOYL)ARYLAMIDOXIMES, Tetrahedron letters, 37(18), 1996, pp. 3113-3116
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
18
Year of publication
1996
Pages
3113 - 3116
Database
ISI
SICI code
0040-4039(1996)37:18<3113:OOABHA>2.0.ZU;2-R
Abstract
The oxidation of arylamidoximes X-C6H4C(NH2)=N-OH (X = H, Me, Cl, NO2, MeO) by H2O2 in the presence of horseradish peroxidase under mild con ditions (phosphate buffer pH 7.4, room temperature) yields the corresp onding O-(arylimidoyl)arylamidoximes in 30-70% yields. The structure o f one of them is established by an X-ray analysis. Copyright (C) 1996 Elsevier Science Ltd